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What is the Chlorodiphenylphosphine ?
Chlorodiphenylphosphine is Colorless to light yellow liquid, while it's Molecular Formula is C12H10ClP. Chlorodiphenylphosphine is used to introduce the diphenylphosphinyl moiety by aryl ortho-lithiation. It is also used as an intermediate to make antioxidants, flame retardants, stabilizers, catalysts, photoinitiators, and optical brighteners. Used as a halogenation reagent for the conversion of alcohols into halides, in the preparation of solid-phase reagent for the conversion of alcohols to alkyl halides.
What is the CAS number for Chlorodiphenylphosphine ?
The CAS number of Chlorodiphenylphosphine is 1079-66-9.
More information of Chlorodiphenylphosphine 1079-66-9 are:
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Synonyms |
Phosphinouschloride, diphenyl- (6CI,8CI,9CI);Chlorodiphenylphosphine;Diphenylchlorophosphine;Diphenylphosphine chloride;Diphenylphosphinouschloride;Diphenylphosphorus chloride;NSC 60407;Phosphine, chlorodiphenyl-; |
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CAS?Number |
1079-66-9 |
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Molecular Formula |
C12H10ClP |
|
Molecular Weight |
220.638 |
|
Density |
1.229 g/mL at 25 °C(lit.) |
|
Melting Point |
14-16 °C |
|
Boiling Point |
319.998 °C at 760 mmHg |
|
Flash Point |
147.33 °C |
|
HS CODE |
HOSPHINE PRODUCT IDENTIFICATION |
|
PSA |
13.59000 |
|
LogP |
3.27310 |
What is Chlorodiphenylphosphine (1079-66-9) used for?
Chlorodiphenylphosphine is a versatile reagent widely used in organic and organometallic synthesis, particularly for introducing diphenylphosphino groups into various substrates. It plays a key role in the synthesis of chiral ligands, such as (R)-SpiroBIP for asymmetric hydrogenation, and in forming N-phosphinyl imines for stereoselective amino sugar production. Additionally, it is employed in the preparation of heterobimetallic complexes and phosphino-carborane derivatives, demonstrating its utility in catalysis and coordination chemistry. Its reactivity with nucleophiles, such as lithiated intermediates, makes it valuable for constructing phosphorus-containing frameworks in diverse applications.
InChI:InChI:1S/C12H10ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
Articles related to Chlorodiphenylphosphine:
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Article |
Source |
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Facial conversion of secondary phosphine oxides R1R2P(O)H to chlorophosphines R1R2PCl by acetyl chloride |
Zhang, Jian-Qiu,Yang, Shangdong,Han, Li-Biao , (2020) |
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Monoacylphosphine oxides with substituents in the phosphonyl moiety as Norrish I photoinitiators: Synthesis, photoinitiattion properties and mechanism |
Duan, Haodong,Gao, Jun,Han, Yuxi,Leng, Kangwei,Li, Qianmin,Liu, Dayong,Wang, Zhongwei,Xu, Xiaolei,Yu, Qing , (2021/09/07) |
How to get the best price on Chlorodiphenylphosphine?
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